Title of article
Crystal structure and electrical conductivity of [NH4+][18-crown-6][Ni(dmit)2]3
Author/Authors
Akutagawa، نويسنده , , T. and Nakmaura، نويسنده , , T. and Inabe، نويسنده , , T. and Underhill، نويسنده , , A.E.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1997
Pages
2
From page
1861
To page
1862
Abstract
The [NH4+][Ni(dmit)2]3 complex, containing a macrocyclic molecule of 18-crown-6-ether (18C6), was obtained as [NH4+][18C6][Ni(dmit)2]3. This salt showed semiconducting behaviour with room temperature conductivity of 0.4 Scm−1. The crystal is composed of segregated non-uniform stack of Ni(dmit)2 and isolated ion-captured cavity of [NH4+][18C6]. The NH4+ ion was fully included in a cavity, and was tightly bounded through strong hydrogen bonds to the oxygen atoms of 18C6.
Keywords
Electrocrystallisation , Transport measurements , Hall effect , Conductivity , megnetotransport , Organic conductors based on radical cation and/or anion salts
Journal title
Synthetic Metals
Serial Year
1997
Journal title
Synthetic Metals
Record number
2071184
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