Title of article
Synthesis and properties of trimethylenedithio-bridged tetrathiafulvalenophanes
Author/Authors
Takimiya، نويسنده , , K. and Aso، نويسنده , , Y. and Otsubo، نويسنده , , T.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1997
Pages
2
From page
1891
To page
1892
Abstract
Three isomeric tetrathiafulvalenophanes possessing two trimethylenedithio spacers have been synthesized and characterized by use of 1H NMR spectroscopy, cyclic voltammetry, and an X-ray structural analysis. Electrocrystallization of three isomers gave the same radical cation salt of trans-trans isomer with PF6 anion, which showed a moderate conductivity with semiconductive temperature dependence. The molecular and crystal structure of the neutral and radical cationic trans-trans isomer were characterized by an X-ray analysis.
Keywords
coupling reactions , Electrocrystallization , Organic conductors based on radical cation salts
Journal title
Synthetic Metals
Serial Year
1997
Journal title
Synthetic Metals
Record number
2071199
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