Title of article
The metallic state in a MMX-chain complex, Pt2(dta)4I
Author/Authors
Kitagawa، نويسنده , , Hiroshi and Onodera، نويسنده , , Noriaki and Ahn، نويسنده , , Jeung-Sun and Mitani، نويسنده , , Tadaoki and Toriumi، نويسنده , , Koshiro and Yamashita، نويسنده , , Masahiro، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1997
Pages
2
From page
1931
To page
1932
Abstract
Transport, optical, magnetic, and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt2(dta)4I (dta = CH3CS2−) were investigated. This complex exhibits metallic conduction between 300 and 340 K, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, a metal-semiconductor transition was observed. This salt undergoes an order-disorder phase transition at 340 K. The mixed-valence state is discussed.
Keywords
Order-Disorder Phase Transition , Pt Complex , MX-chain , mixed valence , metal-insulator transition , HMMC
Journal title
Synthetic Metals
Serial Year
1997
Journal title
Synthetic Metals
Record number
2071216
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