Author/Authors :
Konarev، نويسنده , , D.V. and Valeev، نويسنده , , E.F. and Slovokhotov، نويسنده , , Yu.L. and Shulʹga، نويسنده , , Yu.M. and Roschupkina، نويسنده , , O.S. and Lyubovskaya، نويسنده , , R.N.، نويسنده ,
Abstract :
The reaction of C60 with asymmetric donor tetramethylenedithiodimethyl-tetrathiafulvalene (TMDTDM-TTF) in CS2 yields the (TMDTDM-TTF)2C60(CS2)3 (I) molecular complex. The study of the crystal structure of I reveals that it has a layered structure with alternating sheets of C60 and donor dimers. X-ray photoelectron spectroscopy (XPS) and IR spectroscopy show a weak charge transfer in this compound.
Keywords :
infrared and Raman spectroscopy , Photoelectron spectroscopy , X-ray diffraction , Single-crystal growth , Fullerenes and derivatives