Author/Authors :
Botta، نويسنده , , C. and Treviganti، نويسنده , , R. and Bongiovanni، نويسنده , , G. Dalle Mura، نويسنده , , A. and Tubino، نويسنده , , R.، نويسنده ,
Abstract :
The optical properties and the photoexcitation dynamics of quasi-planar thiophene oligomers included in perhydrotriphenylene are reported. The spectroscopical properties of different oligothiophene conformers are studied with both cw site selective and time resolved photoluminescence measurements. A fast torsional relaxation in the excited state before radiative recombination is proposed as the main photoexcitation mechanism.