Author/Authors :
Triki، نويسنده , , S. and Bérézovsky، نويسنده , , F. and Pala، نويسنده , , J. Sala and Riou، نويسنده , , Renata A. and Molinié، نويسنده , , P.، نويسنده ,
Abstract :
Combination of the magnetic dinuclear chromium(III) anion [Cr2(C2O4)(NCS)8]4 with the organic ET π-donor (ET= BEDT-TTF = bis(ethyienedithio)tetrathiafulvalene) yields two novel molecular hybrids (ET)n[Cr2(C2O4)(NCS)8] (1: n = 5; 2: n = 8). The particular arrangement of the organic units in the former leads to an unprecedented two-dimensional organic sublattice nearly similar to that observed in κ-phase structures. The packing of the ET units in 2 is near that observed in β-phase.
Keywords :
Electrocrystallization , Magnetic measurements , Molecular materials , crystal structure
