Author/Authors :
Kawashima، نويسنده , , T. and Manabe، نويسنده , , T. and Yamashita، نويسنده , , M. and Toriumi، نويسنده , , K. and Kitagawa، نويسنده , , H. and Mitani، نويسنده , , T. and Otamoto، نويسنده , , H. and Inoue، نويسنده , , K. and Hosokoshi، نويسنده , , Y. and Shiro، نويسنده , , M.، نويسنده ,
Abstract :
We synthesized new halogen-bridged mixed-metal complexes [Cu(chxn)2] [PtX2(chxn)2]X4 (X=C1, Br), and measured magnetic susceptibilities. The structures of [Cu(chxn)2][PtX2(chxn)2]X4 consist of linear chains with CuII···X-PtIV repeating units, which have tight hydrogen-bonds between ligands and counter anions and construct a twodimensional(2-D) hydrogen-bond network. Magnetic susceptibility measurements show weak antiferromagnetic behavior.
