Title of article
Conductive complexes of [Ni(dmid)2] with TTF, TMTTF, and ET
Author/Authors
Kazheva، نويسنده , , O.N. and Alexandrov، نويسنده , , G.G. and Dyachenko، نويسنده , , O.A. and Zinenko، نويسنده , , T.N. and Kravchenko، نويسنده , , A.V. and Starodub، نويسنده , , V.A. and Khotkevich، نويسنده , , A.V.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2006
Pages
5
From page
251
To page
255
Abstract
Three charge-transfer salts of [Ni(dmid)2]− (dmid: 1,3-dithiol-2-one-4,5-dithiolate)—TMTTF[Ni(dmid)2], TTFx[Ni(dmid)2] and ETx[Ni(dmid)2] (TMTTF: tetramethyl-tetrathifulvalene, TTF: tetrathifulvalene, ET: bis(ethylenedithio)-tetrathiafulvalene) are prepared and characterized. The TMTTF[Ni(dmid)2] complex has a structure with mixed packs is formed by cations and anions, which alternate each other with subsequent shift. This compound is semiconductor with the room-temperature conductivity of 2.2 × 10−3 Ω−1 cm−1. The TTFx[Ni(dmid)2] and ETx[Ni(dmid)2] complexes have a highest conductivity: σRT 1.86 and 0.54 Ω−1 cm−1, respectively.
Keywords
charge-transfer salts , 1 , 3-dithiol-2-one-4 , 5-dithiolate , crystal structure , electrical conductivity
Journal title
Synthetic Metals
Serial Year
2006
Journal title
Synthetic Metals
Record number
2083072
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