Acrylic blends based on polyaniline. Factorial design

Processable conducting materials for large-scale utilization were prepared by mechanical mixing of polyaniline (PANI) paste and commercially acrylic resin. Doped PANI with organic phosphorus acid was synthesized. These blends can be used for the production of semiconductive paints with good corrosion resistance. By mixing doped PANI with commercially acrylic acid (SMP 63 AZUR SA) hard semiconducting and low elastic films are obtain. The effect of four variables was simultaneously studied: PANI (concentration), stirring speed (ST), mixing time (MT), dispersing agent (DA). Due to the number of variables, a factorial-design was chosen in order to reduce the number of experiments required in order to obtain coatings with high hardness and elasticity and semiconductive behavior. The results indicated that the influences of control factors decrease in order: PANI (concentration), mixing time (MT), dispersing agent (DA) and stirring speed (ST). From the studied variables, the resistance is significantly influenced by the two control factors PANI and MT.