Bi-functional electroluminescent and photovoltaic devices based on rubrene-doped poly(3-hexylthiophene):1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 blends

Electroluminescence and photovoltaic properties were observed simultaneously in a small molecular rubrene-doped poly(3-hexylthiophene):1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 blends based organic solar cells (OSCs). With optimized rubrene doping ratio, the device showed photovoltaic (PV) property with a power convention efficiency 1.05% under illumination and electroluminescence (EL) characteristics with a maximum luminance 65 cd/m2 at higher bias, respectively. It provides a new route to realize the PV and EL bi-functional organic devices. In addition, the EL imaging in OSCs is expected to provide valuable information in the film defect conditions for understanding the blends internal conditions, meliorating the film quality, and further improving the device performance.