Author/Authors :
B. and Vasylets، نويسنده , , Grygorii Y. and Starodub، نويسنده , , Vladimir A. and Barszcz، نويسنده , , Boles?aw and Graja، نويسنده , , Andrzej and Medviediev، نويسنده , , Volodymyr V. and Shishkin، نويسنده , , Oleg V. and Bukrinev، نويسنده , , Alexander S.، نويسنده ,
Abstract :
Three new anion-radical TCNQ salts with Zn and Ni 2,2′-bipyridine complexes and appropriate solvent were synthesized as well as structurally and spectrally investigated. Two of the salts show quasi-one dimensional organization of the anions and show distinct anisotropy of the polarized reflection spectra. Both infrared and Raman spectra were extensively investigated using various spectral methods and discussed. The origin of principal absorption IR bands as well as Raman scattering lines was explained according to our quantum chemical calculations.
Keywords :
crystal structure , chemical synthesis , Fourier transform infrared spectroscopy , Organic compounds , Raman spectroscopy and scattering
