Title of article
Establishment of a linear correlation between the LUMO levels of fullerenes and the Hammett constants of substituents installed: An experimental and theoretical study
Author/Authors
Zhang، نويسنده , , Xuan and Ma، نويسنده , , Lixia and Li، نويسنده , , Xu-Dong، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2014
Pages
4
From page
357
To page
360
Abstract
The LUMO levels of series fulleropyrrolidines equipped with electron-withdrawing and electron-donating groups were determined by electrochemical study and DFT calculation. A linear correlation between the LUMO levels of fullerenes and the Hammett constants of substituents installed was established for the first time. This may allow to predicting and finely tuning the LUMO level of fullerene electron-acceptor.
Keywords
LUMO level , electron acceptor , substituent effect , Fullerene
Journal title
Synthetic Metals
Serial Year
2014
Journal title
Synthetic Metals
Record number
2091957
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