• Title of article

    Structural characterization of lead (II) oxybromide Pb3O2Br2

  • Author/Authors

    Berdonosov، نويسنده , , P.S. and Dolgikh، نويسنده , , V.A. and Popovkin، نويسنده , , B.A.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1996
  • Pages
    6
  • From page
    717
  • To page
    722
  • Abstract
    The lead (II) oxybromide Pb3O2Br2 has been prepared by solid state reaction between PbO and PbBr2 and its structure has been characterized by means of X-ray powder diffraction. The compound is crystallized in the orthorhombic system in space group Pnma, the lattice constance are: a = 12.252(3), b = 5.873(1), c = 9.815(3) إ. The structure of Pb3O2Br2 is built up of the distorted edgeshared [Pb4O] tetrahedra forming the doubled infinite chains parallel to [010]. These chains are mutually connected by Br atoms. A comparison with other Pb3O2X2 (X = Cl, I) substances is presented.
  • Keywords
    A. halides , D. Crystal structure , C. X-ray diffraction , A. Oxides
  • Journal title
    Materials Research Bulletin
  • Serial Year
    1996
  • Journal title
    Materials Research Bulletin
  • Record number

    2093197