Title of article
Low temperature co-pyrolysis of hexabenzylditinsulfide and selenium. an alternate route to Sn(SxSe1−x)
Author/Authors
Boudjouk، نويسنده , , Philip and Remington Jr.، نويسنده , , Michael P. and Seidler، نويسنده , , Dean J. and Jarabek، نويسنده , , Bryan R. and Grier، نويسنده , , Dean G. and Very، نويسنده , , Brian E. and Jarabek، نويسنده , , Raquel L. and McCarthy، نويسنده , , Gregory J.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
6
From page
2327
To page
2332
Abstract
Benzyl-substituted tin chalcogenides (Bn3Sn)2S (1) and (Bn3Sn)2Se (2) yield polycrystalline-phase pure SnS and SnSe in good ceramic yields when pyrolyzed with S and Se, respectively, at 275°C. Heating mixtures of (1) and elemental selenium produce solid solutions of the formula Sn(SxSe1−x). Combustion analysis showed less than 1% residual carbon in all ceramic products. This methodology allows the complete conversion of tin to tin chalcogenides and eliminates the need to synthesize organosulfur and organoselenium intermediates.
Keywords
A. Inorganic compounds , A. Chalcogenides , B. Chemical synthesis , A. Semiconductors , D. X-ray diffraction
Journal title
Materials Research Bulletin
Serial Year
1999
Journal title
Materials Research Bulletin
Record number
2094677
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