• Title of article

    Neutron diffraction studies of La4BaCu4MO13+δ (M = Ni and Co) oxides

  • Author/Authors

    Shivakumara، نويسنده , , C. and Hegde، نويسنده , , M.S. and Rajagopal، نويسنده , , H. and Sequiera، نويسنده , , A.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    6
  • From page
    2063
  • To page
    2068
  • Abstract
    The structures of La4BaCu4NiO13.20 and La4BaCu4CoO13.35 oxides synthesized in NaOH–KOH flux at 450°C were studied using powder neutron diffraction Rietveld analysis. These oxides crystallize in a tetragonal structure in the P4/m space group with Ni3+ or Co3+ partially occupying 6-coordinated (1a) and 5-coordinated (4j) sites of the La4BaCu5O13+δ system. Increase in oxygen content with Ni and Co substitution is reflected in the increase in unit-cell volume, compared with that of the parent La4BaCu5O13+δ.
  • Keywords
    A. Oxides , B. Chemical synthesis , C. Neutron scattering , D. Crystal structure
  • Journal title
    Materials Research Bulletin
  • Serial Year
    2000
  • Journal title
    Materials Research Bulletin
  • Record number

    2094982