• Title of article

    LixPbII1−2xMIIIxO (M = Al, Fe): A new solid solution series related to yellow PbO

  • Author/Authors

    Tripathy، نويسنده , , Mamata and Mani، نويسنده , , Rohini and Gopalakrishnan، نويسنده , , J.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2006
  • Pages
    7
  • From page
    2244
  • To page
    2250
  • Abstract
    New series of oxides, LixPb1−2xMxO (M = Al, Fe), for 0<x≤0.33 adopting the yellow PbO structure have been synthesized by solid state reaction of Li2CO3, Pb(NO3)2 and Al2O3/FeC2O4·2H2O in air at 650–680 °C. Optical absorption spectra reveal systematic increase/decrease of electronic band gap Eg for the Al/Fe members as compared to the parent yellow PbO. Partial deintercalation of lithium occurs under oxidative conditions (Br2/CH3CN) with both the series.
  • Keywords
    A. Oxides , C. X-ray diffraction , B. Chemical synthesis , D. Optical properties
  • Journal title
    Materials Research Bulletin
  • Serial Year
    2006
  • Journal title
    Materials Research Bulletin
  • Record number

    2098017

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2098017