Author/Authors :
Page، نويسنده , , Katharine and Schade، نويسنده , , Christina S. and Zhang، نويسنده , , Jinping and Chupas، نويسنده , , Peter J. and Chapman، نويسنده , , Karena W. and Proffen، نويسنده , , Thomas and Cheetham، نويسنده , , Anthony K. and Seshadri، نويسنده , , Ram، نويسنده ,
Abstract :
We report a non-aqueous solution preparation of Pd2Sn nanoparticles with sizes near 20 nm. The intermetallic compound with the Co2Si structure has been characterized using transmission electron microscopy, Rietveld refinement of synchrotron X-ray and neutron powder diffraction, and real-space pair distribution function analysis of high-energy synchrotron X-ray scattering. We also present a description of the electronic structure of this covalent intermetallic using density functional calculations of the electronic structure.
Keywords :
A. Intermetallic compounds , C. Neutron scattering , C. X-ray diffraction , C. Electron microscopy