Title of article :
A highly selective dual mode detection of Fe3 + ion sensing based on 1,5-dihydroxyanthraquinone in the presence of β-cyclodextrin
Author/Authors :
Mohandoss، نويسنده , , Sonaimuthu and Maniyazagan، نويسنده , , Munisamy and Stalin، نويسنده , , Thambusamy and Srinivasan، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2015
Pages :
9
From page :
94
To page :
102
Abstract :
1,5-Dihydroxyanthraquinone (1,5-DHAQ) and in the presence of β-cyclodextrin (β-CD) has been used to find Fe3 + ion in aqueous solution by UV–visible and fluorescence spectroscopy. The chromo-fluorogenic probe undergoes absorption and emission intensity enhancement upon binding to Fe3 + ion in pH ~ 7 aqueous solutions. The enhancement of the chemosensor probe is attributed to a 1:1 inclusion complex formation between β-CD and 1,5-DHAQ, which has been utilized as the basis for selective detection of Fe3 + ion. The chemosensors can be applied to the selectivity and sensitivity analysis which showed that the remarkable sensing limit of detection (LOD) was 7.3 ∗ 10− 7 M (β-CD/1,5-DHAQ:Fe3 +). The proposed chemosensors based on 1,5-DHAQ and in the presence of β-CD has a good selectivity, sensitivity and potential application to the determination of Fe3 + ion in environmental and biological systems.
Keywords :
?-Cyclodextrin , 1 , Real sample analysis , Chemosensors , Jobיs plot analysis , 5-Dihydroxyanthraquinone
Journal title :
Materials Science and Engineering C
Serial Year :
2015
Journal title :
Materials Science and Engineering C
Record number :
2105595
Link To Document :
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