Structure–property relationships in conjugated molecules

Conjugated dendrimers are ideal materials to study the structure–property relationships in conjugated molecules. We have developed a family of dendrimers that contain t-butyl surface groups, stilbene dendrons, and luminescent cores. For porphyrin and tris(distyrylbenzenyl) amine cored dendrimers cyclic voltammetry (CV) showed that the redox processes occurred at the core. Combining the results from the CV experiments with the device characteristics it was determined that for the dendrimers the cores were held further away from each other with increasing generation. For the amine cored dendrimers it was found that the hole mobility decreased with generation, which is consistent with the cores being further apart. We also found for the amine cored dendrimers that the decrease in hole mobility was matched with increase in device efficiency.