Mechanical relaxation in glasses

The basic properties of glasses and the characteristics of mechanical relaxation in glasses were briefly reviewed, and then our studies concerned were presented. Experimental methods adopted were viscosity, internal friction, ultrasonic attenuation, and Brillouin scattering measurements. The specimens used were several kinds of inorganic, organic, and metallic glasses. The measurements were mainly carried out from the room temperature up to the glass transition temperature, and the relaxation time was determined as a function of temperature. The “double relaxation” composed of two Arrhenius-type relaxations was observed in many materials. In both relaxations, the “compensation effect” showing a correlation of the pre-exponential factor and the activation energy was observed. These results were explained by considering the “complex relaxation” due to cooperative motions of atoms or group of atoms. Values of activation energy near the glass transition determined by the various experimental methods were compared with each other.