Microstructural response of an Al-modified Ni–Cr–Fe ternary alloy during thermal processing

A thermodynamic package was used to predict the phase transformations that occurred during thermal processing of a superalloy based on the composition of a ternary Ni–Cr–Fe alloy. The effect of the addition of 6 w/o Al on phase transformation in the material sintered were estimated and compared with results obtained experimentally by X-ray diffraction and metallography, while the transformation temperature of the modified alloy was corroborated by differential scanning calorimetry (DSC). Mechanical property of the alloy was estimated in terms of Vickers hardness. These results suggest that despite potential problems encountered in high-temperature powder processing of superalloys that often tend to influence the feasibility of using thermodynamic predictions to model such alloy systems, the software and predictions used in this study offer a way to simulate both design and characterisation of the experimental alloy.