Effect of heat treatment on microstructure and mechanical properties of ZrC particles reinforced tungsten-matrix composites

A 20 vol.% ZrCp/W composite is fabricated by hot-pressing, and its mechanical properties can be significantly improved by the addition of ZrC particles. On the other side, the residual pores within ZrC particles clustering regions which are some latent microcrack sources are mainly caused by the relative low sinterability of ZrC particles. In order to eliminate the pores within the particle clusters, the as-sintered composite is annealed at 2300 °C for 1 h. The microstructure of the annealed composite becomes more uniform and densified. Components of the as-sintered and annealed composites are composed of a dilute solid solution tungsten-matrix, (Zr, W)C solid solution particles and a new W2C phase, but the content of W2C phase in the annealed composite increases. After annealing, the strength properties of the composite decrease, but its plasticity increases.