Effect of nitrogen addition and annealing temperature on superelastic properties of Ti–Nb–Zr–Ta alloys

The composition dependence of the mechanical properties and martensitic transformation behavior of Ti–Nb–4Zr–2Ta–N alloys is investigated. The effect of annealing temperature on the microstructural evolution and superelastic properties in the N-added and N-free alloys is compared. The addition of N decreases Ms of Ti–Nb–4Zr–2Ta alloys by about 200 K per 1 at.%N and improves the superelastic properties of Ti–Nb–4Zr–2Ta alloys. The dissolution of α phase increases the martensitic transformation start temperature and decreases the superelastic recovery strain for the N-free alloy, whereas it causes opposite effects for the N-added alloy. The different annealing temperature dependences of superelastic properties are discussed on the basis of microstructure observation.