Title of article
Sonochemical hydrosilylation of 2-substituted cyclohexanones in the presence of Wilkinson complex
Author/Authors
B. Felfoldi، نويسنده , , K?roly and Sz?ri، نويسنده , , Kornél and T?r?k، نويسنده , , Béla and Bart?k، نويسنده , , Mih?ly، نويسنده ,
Issue Information
فصلنامه با شماره پیاپی سال 2000
Pages
3
From page
15
To page
17
Abstract
The sonochemical hydrosilylation of alkyl substituted cyclohexanones catalyzed by Rh(PPh3)3Cl is described. The application of ultrasonic irradiation during the reaction highly enhances the reaction rates and produces higher yields than those obtained in silent reactions. The stereoselectivity of the reaction has not been changed, the isomeric distribution, i.e. the cis/trans ratio of the 2-substituted cyclohexanols formed, is very close to those obtained in conventional stirred reactions.
Keywords
Wilkinson complex , Hydrosilylation , 2-Substituted alkyl cyclohexanones , Ultrasound
Journal title
Ultrasonics Sonochemistry
Serial Year
2000
Journal title
Ultrasonics Sonochemistry
Record number
2188281
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