Transition from mildly-tholeiitic to calc-alkaline suite: the case of Chichontepec volcanic centre, El Salvador, Central America

The Chichontepec volcano is a Plio-Pleistocene composite volcano that erupted lavas ranging from high-alumina basalts to dacites. It experienced a caldera-forming paroxysmal eruption during the early Pleistocene. Pre-caldera lavas are mildly tholeiitic and they evolved mainly by low pressure crystal fractionation, notwithstanding the fact that most mafic lavas (low-MgO high-alumina basalts) retain traces of polybaric evolution. Conversely, post-caldera lavas, which are mainly pyroxene andesites, are clearly calc-alkaline, having evolved by open-system crystal fractionation. Sr–Nd isotopic data and trace elements characteristics indicate that the same mantle source was involved in the petrogenesis of these series. Modelling the AFC process showed that it did not play any role in the petrogenesis of these rocks; a crystal fractionation model is considered to be more relevant. A slight variation in the fractionating assemblage could have caused the transition from an early mildly tholeiitic trend to a late calc-alkaline one. Mineralogical evidence, mass-balance calculations and elemental chemistry support this hypothesis, assuming that the greater amount of pyroxene on the liquidus is at the expense of plagioclase; this would have prevented the trend in iron enrichment.