Spectrometric investigation of the weathering process affecting historical glasses of Leَn Cathedral, Spain

Atmospheric pollution plays important roles in the weathering of the historical buildings and glass windows. Samples of white powdered weathering products, recovered during restoration of the stained-glass windows of Leَn Cathedral in Spain, were characterised using a combination of scanning electron microscopy (SEM) with energy dispersive-X ray spectrometry (ED-XRS), Fourier transform-infrared (FT-IR) spectroscopy and Raman spectrometry. The presence of sulphates, and to a lesser extent carbonates, in the white powdered product is clear indication of the participation of atmospheric acidifying gases, particularly SOx, in the weathering process. It is interesting to note that there was no indication of the participation of NOx gases. There was, however, evidence that the putty and mortar used to seal/join the glasses were major sources of the weathering products. In this way, this study suggests sealants more resistant to oxidation, such as silicone- and zirconia-based materials, should be considered for repairing glass windows in historic buildings to avoid exacerbating degradation.