Implications for air quality and the impact of financial and economic crisis in South Spain: Geochemical evolution of atmospheric aerosol in the ceramic region of Bailén

A temporal series study of atmospheric aerosol was performed over the last ten years (2003–2012) in an urban background monitoring station with ceramic industrial influence, in Bailén, SE Spain. Temporal trends of major and minor chemical components of PM10 for a long term data series were investigated, showing that PM10 concentrations have been steadily decreasing over almost a decade, with a statistical significance. Measurements indicate a reduction of elements and components related to the industrial activity of brick-ceramic production (V, Cd, Rb, La, Cr, Ni, As, Pb and SO42−). Conversely, Cu levels define an increasing trend from the beginning of the study period but with the highest step trend since 2011–2012, coinciding with the beginning of the financial and economic crisis in 2008. A similar time evolution pattern of Cu and OC, EC, and K levels may be a tracer of domestic local combustion source, and a new biomass burning source has been identified. Chemical composition of olive tree logs suggest as the combustion of wood with high concentration of Cu can imply an increase of Cu concentration in the atmospheric particles compared with other sources such as traffic.