Boron in central Andean ignimbrites: implications for crustal boron cycles in an active continental margin

Calc-alkaline pumices and lavas from the Neogene–Pleistocene central Andean Altiplano–Puna Volcanic Complex (APVC) contain quartz phenocrysts with abundant primary melt inclusions. Melt inclusions represent the melt composition of dacitic to rhyodacitic magmas prior to eruption and they are widely protected from eruptive degassing, low-temperature vapor-phase alteration and post-depositional contamination with boron-rich dusts and aerosols. The average boron isotopic compositions of melt inclusion and matrix glasses are uniform in the units studied (overall average δ11B=−3.8±2.8‰, 1 SD) and overlap with the range of local basement rocks (δ11B=−11‰ to −5‰). B is enriched in glasses (55±14 ppm, 1 SD), whereas whole-rock contents range between 10 and 40 ppm. At similar B contents, incompatible trace element ratios like B/Nb are generally higher in the ignimbrites and lavas (B/Nb=2.4 and 4.0) than in crustally derived Paleozoic to Cretaceous granitoids from NW-Argentina (B/Nb=1.0–2.7). This suggests a minor contribution of high-B/Nb arc andesites and is consistent with petrogenetic models in which APVC dacites originated from hybridization of dominantly crustally derived melts with andesitic magmas. Boron-rich hydrothermal brines and salt-lake water from within the APVC have δ11B=−4.1 to +5.7‰. These values are close to the APVC ignimbrite values and contrast with hydrothermal brines from the eastern Puna and eastern Cordillera, which have lower δ11B=−10‰ to −17‰ and occur in an area of little volcanic cover. This regional pattern suggests that borate enrichments resulted from the leaching of local country rocks: ignimbrites in the W Altiplano–Puna and Paleozoic basement in the eastern Puna and eastern Cordillera.