Determination of goslarite–bianchite equilibria by the humidity-buffer technique at 0.1 MPa

Goslarite–bianchite equilibria were determined along four humidity-buffer curves at 0.1 MPa and between 27 and 36 °C. Results, based on tight reversals along each humidity buffer, can be represented by ln K (±0.005)=19.643−7015.38/T, where K is the equilibrium constant and T is temperature in K. Our data are in excellent agreement with several previous vapor-pressure measurements and are consistent with the solubility data reported in the literature. Thermodynamic analysis of these data yields 9.634 (±0.056) kJ mol−1 for the standard Gibbs free energy of reaction, which is in good agreement with the value of 9.658 kJ mol−1 calculated from the thermodynamic data compiled and evaluated by Wagman et al. [Wagman, D.D., Evans, W.H., Parker, V.B., Schumm, R.H., Halow. I., Bailey, S.M., Churney, K.L., Nuttal, R.L., 1982. The NBS tables of chemical thermodynamic properties. Selected values for inorganic and C1 and C2 organic substances in SI units. J. Phys. Chem. Ref. Data 11, Suppl. 2].