Structural and magnetic properties and evidence of spin-glass behavior induced by Fe-doping in perovskite manganites B-site

AMn1 − xFexO3 (A = La0.75Ca0.08Sr0.17 and x = 0–0.23) compounds, sintered at 700 °C, were characterized by X-ray diffraction (XRD) at room temperature. Rietveld refinement has shown that samples can be indexed in the orthorhombic (Pnma) structure for low Fe-content (x ≤ 0.046) and rhombohedral ( R - 3 c ) structure for high Fe-content (x ≥ 0.115). The transmission Mössbauer spectra have revealed the same isomer shift δ value assigned to Fe3+ ion for all compounds. The magnetization behavior and the Curie temperature TC have shown a large dependence on the fractional composition x. In fact, the M(T) curves have revealed the presence of a long-range ferromagnetic state below TC for compounds with x ≤ 0.115, and a spin-glass state (SGS) at low temperature for high Fe-content (x ≥ 0.177).