Radiation aging of nonmetallic materials: specific aspects

Under irradiation, all materials experience various forms of structural evolution, from the simplest, associated with point defect creation and accumulation, to complex phase changes, either towards equilibrium or nonequilibrium structures. In nonmetallic ceramics the same processes are known or probable; however, the nature of bonding, partly ionic and partly covalent, as well as the complexity associated with the long range character of the Coulomb interaction, have long posed great difficulties in defect and aging studies under irradiation. Our aim here is to review the current state of knowledge, stressing the specific characteristics of nonmetallic materials, from primary defect creation to collective behavior, with respect to both experimental facts as well as to modeling perspectives. Given the broad field covered, we will illustrate the problem by choosing a few model materials, mostly oxides, in which the whole spectrum of phenomena has been handled. We will begin with threshold energy studies, then go to microstructure formation and evolution, radiation enhanced diffusion results, and lastly to phase changes. To cite this article: Y. Limoge, C. R. Physique 9 (2008).