Inorganic carbon in the central California upwelling system during the 1997–1999 El Niño–La Niña event

Sea surface pCO2 was monitored during 49 cruises from February 1997 to December 1999 along a section perpendicular to the central California Coast. Continuous measurements of the ocean–atmosphere difference of pCO2 were made on a mooring in the same region from July 1997 to December 1999. The El Niño/La Niña cycle of 1997–1999 had a significant influence on local ocean–atmosphere CO2 transfer. During the warm anomaly associated with El Niño, upwelling was suppressed and average sea surface pCO2 was below atmospheric level. High rainfall and river runoff in the late winter and early spring of 1998 produced areas where pCO2 was depressed by as much as 100 μatm. A flux ranging from 0.3 to 0.7 mol C m−2 y−1 from the atmosphere into the ocean was estimated for the El Niño period from wind and ΔpCO2 data. Temperatures and upwelling returned to near normal in the summer of 1998, but a cold anomaly developed during autumn of that year. Temperature and pCO2 data indicate that upwelling continued throughout much of the 1998–1999 winter and intensified significantly in the spring of 1999. During strong upwelling events, the estimate of ocean to atmosphere flux approached rates of 50 mol C m−2 y−1. The estimate for the average CO2 flux from July 1998 to July 1999 was 1.5–2.2 mol C m−2 y−1 from the ocean to the atmosphere. While the flux estimate for the El Niño time period may be applicable to a larger area, the high ocean to atmosphere fluxes during La Niña might be the result of sampling near a zone of intense upwelling.