Author/Authors :
Sayahi1، M. H. نويسنده 1 Department of Chemistry, Payame Noor Universtiy (PNU), P.O. Box 19395-3697, Tehran, Islamic Republic of Iran , , Mirza، B. نويسنده 2 Department of Applied Chemistry, Faculty of science, Islamic Azad University, Tehran, Islamic Republic of Iran ,
Abstract :
A novel and efficient palladium-based homogeneous catalyst was fabricated and used as a robust catalyst in Suzuki–Miyaura cross-coupling and Heck reactions. 2-Amino-N-(pyridin-2-ylmethyl)benzamide was introduced as a versatile ligand for palladium-catalyzed cross-coupling reactions. The desired active and stable homogeneous Pd catalyst was prepared via the coordination of Pd with 2-amino-N-(pyridin-2-ylmethyl)benzamide and fully characterized. The catalyst exhibited excellent activity in Suzuki–Miyaura cross-coupling and Heck reactions. The proposed protocol featured mild reaction conditions and efficiency using LiOH as base.
