The role of wildfire and gully erosion in particulate Pb export from contaminated peatland catchments in the southern Pennines, U.K.

The near-surface layer of peatlands of the Peak District, southern Pennines, UK, is severely contaminated with atmospherically deposited Pb. Contemporary catchment soil Pb inventories at Upper North Grain and Torside Clough reveal that ∼ 23% and ∼ 54%, respectively, of the potential store of Pb in each catchment has been lost through erosion of the contaminated near-surface peat layer. Soil Pb inventories and the Pb content of suspended sediments reveal that, in both catchments, the main mechanism for contemporary particulate Pb export is gully erosion. Historical sheet erosion on bare peat flats at Torside Clough has released significant quantities of Pb into the fluvial system, triggered by the exposure of the near-surface peat during an accidental wildfire in 1970. Up to 32% of the total Pb export from the catchment may have been released during a discrete erosion event soon after the wildfire. Accidental wildfires and the subsequent release of highly contaminated peat into the southern Pennine fluvial system may increase under predicted climate change scenarios.