Adsorption of rhenium(VII) on 4-amino-1,2,4-triazole resin

The adsorption properties of 4-amino-1,2,4-triazole resin (4-ATR) for Re(VII) were investigated by static and dynamic adsorption–desorption measurements with ultraviolet–visible spectroscopy. The influence of conditions such as temperature, initial solution pH and contact time on the adsorption curve was studied. It was found that the 4-amino-1,2,4-triazole resin was suitable for adsorption of Re(VII). The saturated adsorption capacity was 354 mg·g− 1resin at pH 2.6 in HAc–NaAc medium at 298 K. The adsorption rate constant was k298 = 8.2 × 10− 5 s− 1. The adsorption behavior of 4-ATR for Re(VII) obeyed the Freundlich empirical equation; whilst changes in adsorption with temperature gave an enthalpy change ΔH = − 11.8 kJ·mol− 1. The molar ratio of the functional group of 4-ATR to Re(VII) was about 2:1. Re(VII) adsorbed on 4-ATR was eluted by 1.0 ~ 5.0 mol·L− 1 HCl with 100% quantitative elution in 4.0 mol·L− 1 HCl solution. The resin can be regenerated and reused without apparent decrease in adsorption capacity.