Laboratory studies of methane and ethane adsorption and nucleation onto organic particles: Application to Titanʹs clouds

Titan, Saturnʹs largest moon, has a thick nitrogen/methane atmosphere. The temperature and pressure conditions in Titanʹs atmosphere are such that the methane vapor should condense near the tropopause to form clouds. Several ground-based measurements have observed sparse cloud-like features in Titanʹs atmosphere, while the Cassini mission to Saturn has provided large scale images of the clouds. However, Titanʹs cloud formation conditions remain poorly constrained. Heterogeneous nucleation (from the vapor phase onto a solid or liquid aerosol surface) greatly enhances cloud formation relative to homogeneous nucleation. In order to elucidate the cloud formation mechanism near the tropopause, we have performed laboratory measurements of the adsorption of methane and ethane onto solid organic particles (tholins) representative of Titanʹs photochemical haze. We find that monolayers of methane adsorb onto tholin particles at saturation ratios less than unity. We also find that solid methane nucleates onto the adsorbed methane at a saturation ratio of S = 1.07 ± 0.008 . This implies that Titanʹs methane clouds should form easily. This is consistent with recent measurements of the column of methane ruling out excessive methane supersaturation. In addition, we find ethane adsorbs onto tholin particles in a metastable phase prior to nucleation. However, ethane nucleation onto the adsorbed ethane occurs at a relatively high saturation ratio of S = 1.36 ± 0.08 . These findings are consistent with the recent report of polar ethane clouds in Titanʹs lower stratosphere.