Title of article
Experimental and Quantum Chemical Evaluation of Dihydropyridine Derivative as Environmental Benign Corrosion Inhibitor for Mild Steel in 15% HCl
Author/Authors
R. Ansari, Kashif Department of Chemistry - Indian Institute of Technology - (Banaras Hindu University) , A. Quraishi, Mumtaz Department of Chemistry - Indian Institute of Technology - (Banaras Hindu University)
Pages
14
From page
509
To page
522
Abstract
The behavior of 1,1’-{2, 6-dimethyl-4-[-2-phenylethenyl]-1,4-dihydropyridine-3,5-diyl}diethanone (DHP) have been investigated as mild steel (MS) corrosion inhibitor in 15% HCl solution by gravimetric measurements, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (Tafel), scanning electron microscopy (SEM) analysis. Quantum chemical calculation was applied to correlate electronic structure parameters with the inhibition performances. Adsorption of DHP obeys the Langmuir’s isotherm. Potentiodynamic polarization measurements showed that DHP acted as mixed type inhibitor but cathodically dominant
Keywords
EIS , SEM , Quantum chemical calculation , Mild steel (MS)
Journal title
Astroparticle Physics
Serial Year
2015
Record number
2418639
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