Title of article :
A Study of Effects of Different Surface Modifications of MWCNTs on their Adsorption Capacity of Benzene and Toluene
Author/Authors :
Pourfayaz, Fathollah Department of Renewable Energies and Environment - Faculty of New Sciences and Technologies - University of Tehran , Maleki, Akbar Department of Renewable Energies and Environment - Faculty of New Sciences and Technologies - University of Tehran , Ahmadi-Avval, Parviz Farayand Chemical Research Group - ACECR, Faculty of Engineering, University of Tehran , Haji Tarverdi, Mohammad Sadegh Technology Development Institute - ACECR - Tehran , Ahmadi, Mohammad Hossein Faculty of Mechanical Engineering - Shahrood University of Technology - Shahrood
Pages :
8
From page :
107
To page :
114
Abstract :
Multi-Walled Carbon Nanotubes (MWCNTs) surfaces were serially modified by the annealing treatment under Helium flow at 1000oC, the nitric acid treatment and again the annealing treatment under same conditions and their maximum adsorption capacities for benzene and toluene were measured and analyzed. The unmodified and modified MWCNTs were characterized by Fourier Transform InfraRed (FT-IR) and Raman spectroscopy techniques and Brunauer–Emmett–Teller (BET) specific surface area measurements. The results revealed that the nitric acid treatment leads to form the functional groups and defects on the MWCNTs surfaces and increase their specific surface areas while the annealing treatments remove the functional groups and defects and therefore improve the structural integrity of the MWCNTs and enhance the - interaction between the MWCNTs and the toluene/benzene. According to the measurements of the maximum adsorption capacities, both acid and annealing treatments increased the adsorption capacity of the MWCNTs for both the benzene and toluene. It can be finally concluded that the adsorption capacity of the carbon nanotubes for the aromatic organic adsorbates such as benzene and toluene not only depends on their specific surface area but also is influenced by the structural integrity of the carbon nanotubes.
Keywords :
Aromatic contaminants , Adsorption , Carbon nanotubes , Surface modification
Journal title :
Astroparticle Physics
Serial Year :
2017
Record number :
2428684
Link To Document :
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