Title of article :
PVC-Based Cerium Phosphate Membrane Exhibiting Selectivity for Molybdate Anions
Author/Authors :
Khodakarami, Hassan Department of Chemistry - Faculty of Science - Shahid Beheshti University - Tehran , Ghourchian, Hedayat O Laboratory of Microanalysis - Institute of Biochemistry & Biophysics - University of Tehran - Tehran
Abstract :
A PVC-based membrane containing cerium phosphate was developed. Unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. Therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. The response of molybdate selective electrode based on this membrane was perfectly linear in the concentration range 1.98´10-5 to 10-1 M. Characteristics of this electrode such as electric resistance, stability and membrane preconditioning process, and regeneration of its sensitivity are reported.
Keywords :
Ion-exchange membrane , Membrane electrode , PVC-based membrane , Ion-selective electrode , Molybdate anions , Cerium phosphate
Journal title :
Astroparticle Physics