Title of article :
Theoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides
Author/Authors :
Entezari, Mahdieh Department of Chemistry - Islamic azad university - mahshahr branch, Mahshahr, Iran , Zomorod bakhsh, Shahab Department of Chemistry - Islamic azad university - mahshahr branch, Mahshahr, Iran
Abstract :
The internal strain in cyclic amides are explained as a factor of resonance
that are effected on the bond length C-N and are a major factor of rates
of hydrolysis. The cyclic amides in this study are optimized by Gaussian
program and the bond length of C-N in the rings are studied by HF/6-
31G*.
Keywords :
internal strain , resonance , relative rate hydrolysis , bond length , cyclic amides
Journal title :
Astroparticle Physics
