Title of article
Dynamic 1H-NMR study of synthesized enamines from reaction between isocyanides and N,N'-dimethylbarbituric acid
Author/Authors
Marandi, Ghasem Shahid Bakeri High Education Center of Miandoab - Urmia University, Urmia, Iran. , Maghsoodlou, Malek Taher Department of Organic Chemistry - Faculty of Science - the University of Sistan and Baluchestan, Zahedan, Iran , Moradi, Ashraf Department of Organic Chemistry - Faculty of Science - the University of Sistan and Baluchestan, Zahedan, Iran
Pages
3
From page
1627
To page
1629
Abstract
Reaction of alkyl or aryl isocyanides with N,N'-dimethylbarbituric acid leads to pull-push olefinic systems which exhibit dynamic effects around the formed carbon-carbon double bond. Using this technique free-energy of activation (ΔG‡) were calculated for restricted rotation around the polarized carbon-carbon double bonds.
Keywords
Restricted rotation , Enamines , Polarized carbon-carbon double bonds , Isocyanides
Journal title
Astroparticle Physics
Serial Year
2015
Record number
2435841
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