Title of article :
Fabrication of perovskite-type oxide La0.5Pb0.5MnO3 nanoparticles and its dye removal performance
Author/Authors :
Tavakkoli, Haman Department of Chemistry - Khouzestan Science and Research Branch - Islamic Azad University, Ahvaz , Moayedipour, Tahereh Department of Chemistry - Khouzestan Science and Research Branch - Islamic Azad University, Ahvaz
Abstract :
La0.5Pb0.5MnO3 perovskite-type oxide is prepared
by sol–gel method. The physical and chemical
properties of a nanoparticle were characterized by differential
thermal analysis (DTA), thermogravimetric analysis,
XRD, and scanning electron microscopy (SEM) techniques.
The adsorption effect of the sample is evaluated by
removal of Eosin dye from aqueous solution. The results of
XRD indicate that the perovskite-type oxide has a good
crystal phase at 650 C. The DTA, XRD, and SEM data
revealed that La0.5Pb0.5MnO3 nano particles are prepared
successfully via sol–gel modified pechini method. These
nanoparticles showed the excellent adsorption efficiency
towards Eosin dye in aqueous solution. The adsorption
studies were carried out at different pH values, dye concentrations,
various adsorbent dosages, and contact time in
a batch experiment. The dye removal efficiency was found
to be decreased with increasing in initial pH of the dye
solution, and nanoadsorbent exhibited good dye removal
efficiency at acidic pH specially pH 1. Experimental results
indicated that the adsorption kinetic data follow a pseudofirst-
order rate for tested dye. The isotherm evaluations
revealed that the Freundlich model attained better fits to the
experimental equilibrium data than the Langmuir and
Temkin models.
Keywords :
Perovskite-type oxide , Nanopowder , Dye removal , Eosin
Journal title :
Astroparticle Physics