Title of article :
Sulfuric acid immobilized on silica: A versatile and reusable heterogeneous catalyst for the synthesis of phenanthrimidazole derivatives
Author/Authors :
Behmadi, Hossein Department of Chemistry - Faculty of Basic Sciences - Islamic Azad University - Mashhad Branch , Saadati, Mahdi Young Researchers Club - Islamic Azad University - Mashhad Branch , Roshani, Mina Department of Chemistry - Faculty of Basic Sciences - Islamic Azad University - Mashhad Branch , Mohammadi, Hasan Department of Chemistry - Faculty of Basic Sciences - Islamic Azad University - Mashhad Branch , Razavia, Abbas Department of Chemistry - Faculty of Basic Sciences - Islamic Azad University - Mashhad Branch , Ramezani, Marjan Department of Chemistry - Faculty of Basic Sciences - Islamic Azad University - Mashhad Branch
Abstract :
A new, convenient, efficient, and cost-effective one-pot synthesis of 1Hphenanthro[
9,10]imidazol-2-yl from phenanthraquinone and aldehydes, using sulfuric acid
immobilized on silica as catalyst is described. The present methodology offers several
advantages such as excellent yields, simple procedure, shorter reaction times, the use of
inexpensive reagents, easy recovery and eco-friendly. In addition to these, 2-alkyl
phenanthrimidazole is obtained from triethyl orthoesters in good yields.
Keywords :
1H-phenanthro[9,10]imidazol-2-yl , Phenanthraquinone , Triethyl orthoesters , Sulfuric acid
Journal title :
Astroparticle Physics