• Title of article

    Friedel-crafts alkylation of indoles with epoxides using PW12- APTES@SBA-15

  • Author/Authors

    Aliyan ، Hamid - Islamic Azad University, Shahreza Branch

  • Pages
    9
  • From page
    325
  • To page
    333
  • Abstract
    H3PW12O40 (PW12) was immobilized over mesoporous alumina through the reaction of mesoporous alumina functionalized 3-aminopropyl triethoxy silane (3-APTES) and PW12. The surface properties of the functionalized nanocomposite was analyzed by a series of characterization techniques like elemental analysis, FTIR and XRD. XRD and adsorption–desorption analysis show that the mesostructure of silica remains intact after various modifications, while spectral technique show the successful grafting of the neat PW12 inside the porous silica support. 3-Alkylindole derivatives were produced by ring opening of epoxides in the presence of PW12-APTES@ SBA- 15 nanocomposites as an efficient catalyst. The catalyst can be reused for several times but it will be less active.
  • Keywords
    Friedel , crafts alkylation , indole , epoxide , SBA , 15 , heterogeneous catalysis , polyoxotungstate
  • Journal title
    Iranian Chemical Communication
  • Serial Year
    2018
  • Journal title
    Iranian Chemical Communication
  • Record number

    2461105