Title of article
Application of Acidic Ionic Liquid as a Solvent/Catalyst for Preparation of α-Oximinoketones from β-Dicarbonyl Compounds
Author/Authors
S. Shahvelayati, Ashraf Department of Chemistry - Shahre-rey Branch, Islamic Azad University, Tehran , Yadollahzadeh, Khadijeh Department of Chemistry - Aliabad Katoul Branch, Islamic Azad University, Aliabad Katoul , Sameni, Fatemeh Department of Chemistry - Shahre-rey Branch, Islamic Azad University, Tehran
Pages
10
From page
18
To page
27
Abstract
The selective nitrosation of β-dicarbonyl compounds with sodium nitrite was carried out under1- methyl-3 carboxymethylimidazolium chloride, prepared from N-methylimidazole and chloroacetic acid, as an acidic ionic liquid. The reaction was found to proceed under relatively mild conditions with excellent conversion and selectivity. The ionic liquid was recycled and reused.
Keywords
β-Dicarbonyl compounds , α-Oximinoketones , Acidic ionic liquid , Nitrosation
Serial Year
2017
Record number
2494697
Link To Document