Title of article :
Enantioselective Henry reaction catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand and Cu(II) ion
Author/Authors :
KOZ, Gamze Ege University - Faculty of Science - Department of Chemistry, Turkey , ASTLEY, Demet Ege University - Faculty of Science - Department of Chemistry, Turkey , ASTLEY, Stephen Thomas Ege University - Faculty of Science - Department of Chemistry, TURKEY
Abstract :
Mild and efficient enantioselective Henry reactions of nitromethane with various aldehydes were catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand in the presence of Cu(II) ions, affording the corresponding adducts in high yields (up to 96%) and enantioselectivities (up to 92% ee).
Keywords :
Enantioselective Henry reaction , chiral Schiff base , L , (+) , aspartic acid
Journal title :
Turkish Journal of Chemistry
Journal title :
Turkish Journal of Chemistry