Title of article :
An expedient synthesis of 6-vinylfulvene
Author/Authors :
ERDEN, Ihsan San Francisco State University - Department of Chemistry and Biochemistry, USA , SABOL, Jenny San Francisco State University - Department of Chemistry and Biochemistry, USA , GUBELADZE, Ana San Francisco State University - Department of Chemistry and Biochemistry, USA , RUIZ, Andrea San Francisco State University - Department of Chemistry and Biochemistry, USA
Abstract :
6-Vinylfulvenes constitute a class of fulvenes that are difficult to access due to the lack of a general method for their synthesis. In particular, the unsubstituted parent system has been very difficult to obtain by existing methods. In this communication we describe a convenient 3-step protocol for the synthesis of the title compound by way of sulfide oxidation and subsequent sulfoxide elimination.
Keywords :
Fulvene , vinylfulvene , sulfide , sulfoxide , desulfinylation
Journal title :
Turkish Journal of Chemistry
Journal title :
Turkish Journal of Chemistry