Title of article :
Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole- K N ³ } zinc(II)
Author/Authors :
KÜÇÜKBAY, Hasan İnönü University - Faculty of Arts and Sciences - Department of Chemistry, Turkey , YILMAZ, Ülkü İnönü University - Battalgazi Vocational School, Turkey , AKKURT, Mehmet Erciyes University - Faculty of Science - Department of Physics, Turkey , BÜYÜKGÜNGÖR, Orhan Ondokuz Mayıs University - Faculty of Arts and Science - Department of Physics, Turkey
Abstract :
The Co(II), Fe(II), and Zn(II) complexes of 1-(3-phenyl)propylbenzimidazole (PPBI), 5-nitro-1-(3-phenyl) propylbenzimidazole (PPNBI), 1-[2-(4-morpholinyl)ethyl]benzimidazole (MEBI), 1-[2-(1-piperidinyl)ethyl]benzimidazole (PEBI), and 5-nitro-1-[2-(1-piperidinyl)ethyl]benzimidazole (PENBI) were synthesized and characterized by 1H NMR, 13C NMR, and elemental analyses. The magnitudes of the magnetic moments for paramagnetic complexes were between 4.07 and 5.11 B.M. Moreover, the crystal structure of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H -benzimidazole- K N ³ } zinc(II) was determined by single crystal X-ray diffraction.
Keywords :
Benzimidazole metal complexes , transition metal complexes , coordination compounds , crystal structure
Journal title :
Turkish Journal of Chemistry
Journal title :
Turkish Journal of Chemistry
