Author/Authors :
Abdullah, N. Universiti Teknologi Malaysia - Faculty of Chemical and Energy Engineering, Advanced Membrane Technology Centre (AMTEC), Malaysia , Yusof, N. Universiti Teknologi Malaysia - Faculty of Chemical and Energy Engineering, Advanced Membrane Technology Centre (AMTEC), Malaysia , Jaafar, J. Universiti Teknologi Malaysia - Faculty of Chemical and Energy Engineering, Advanced Membrane Technology Centre (AMTEC), Malaysia , Ismail, A. F. Universiti Teknologi Malaysia - Faculty of Chemical and Energy Engineering, Advanced Membrane Technology Centre (AMTEC), Malaysia , Che Othman, F. E. Universiti Teknologi Malaysia - Faculty of Chemical and Energy Engineering, Advanced Membrane Technology Centre (AMTEC), Malaysia , Salleh, W. N. W. Universiti Teknologi Malaysia - Faculty of Chemical and Energy Engineering, Advanced Membrane Technology Centre (AMTEC), Malaysia , Misdan, N. University Tun Hussien Onn Malaysia - Faculty of Engineering Technology, Malaysia
Abstract :
In this work, activated carbon nanofibers (ACNFs) from precursor polyacrylnitrile (PAN) and manganese oxide (MnO_2) were prepared via electrospinning process. The electrospun PAN/MnO2- based ACNFs were characterized in term of its morphological structure, functional group analysis and specific surface area using SEM-EDX, FTIR and BET analysis respectively. The comparative adsorption study of cadmium (II) ions from aqueous solution between the neat ACNFs, composite ACNFs and commercial granular activated carbon was also conducted. SEM analysis illustrated that composite ACNFs have more compact fibers with presence of MnO_2 beads with smaller fiber diameter of 437.2 nm as compared to the neat ACNFs which is 575.5 nm. BET analysis elucidated specific surface area of ACNFs/MnO_2 to be 67 m_2/g. Under adsorption study, it was found out that Cd (II) removal by ACNFs/MnO_2 was the highest (97%) followed by neat ACNFs (96%) and GAC (74%).
