Title of article :
Physicochemical Characteristics of Malaysian Crude Palm Kernel Oil
Author/Authors :
Bahadi, Murad Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia - Faculty of Education - Hadhramout University - Hadhramout, Yemen , Firdaus Mohamad Yusoff, Mohamad Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia , Salimon, Jumat Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia , Ahmed Jumaah, Majd Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia , Derawi, Darfizzi Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia
Abstract :
This study was carried out to determine the physicochemical properties of Malaysian crudepalm kernel oil (CPKO). The physicochemical properties showed that the free fatty acid(FFA%) of 3.7±0.1%, acid value of 10.4±0.1 mg/g, iodine value of 20.8±0.6 mg/g, hydroxylvalue of 45.06±0.3 mg/g, refractive index at 28°C of g/ml, 1.455, moisturecontent of0.5±0.1%, viscosity at 28°C of 40 cP, Lovibond colour (R/Y) at 28°C of 0.5R–20Y. The gaschromatography-flame ionisation detector was used to determine the fatty acid composition inCPKO. The results showed that the dominant fatty acids are lauric acid (44.5±0.7%), oleic acid(18.0±0.5%), myristic acid (16.9±0.1%) and palmitic acid (9.4±0.2%). The majortriacylglycerols (TAGs) of CPKO estimated using high-performance liquid chromatographywere LaLaLa (32.91%), LaLaM (23.59), LaOLa (9.93%) and CLaLa (9.10%). The differentialscanning calorimetry showed that the crystallisation of CPKO displayed two major exothermicregions of CPKO with the saturated TAG at 6.11°C and the unsaturated TAG at-2.10°C. Themelting curve of CPKO displayed two endothermicpeak regions at 9.13°C and 24.08°C.
Keywords :
crude palm kernel oil , physicochemical characteristic , triacylglycerol profile , fatty acid composition , thermal behaviour
Journal title :
Malaysian Journal of Chemistry